Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 69, Pages 8652-8655Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03013b
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An efficient copper-catalyzed radical ring-opening halogenation with HX (aq) as the reaction condition has been developed. This protocol features redox-neutral conditions, green halogen sources, and a broad substrate scope, providing practical access to distally chlorinated, brominated and iodinated alkyl ketones and alkyl nitriles with moderate to good yields.
An efficient copper-catalyzed radical ring-opening halogenation with HX (aq) is described. This protocol features redox-neutral conditions, green halogen sources, and a broad substrate scope, providing practical access to distally chlorinated, brominated and iodinated alkyl ketones and alkyl nitriles with moderate to good yields.
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