Journal
CRYSTENGCOMM
Volume 23, Issue 33, Pages 5569-5574Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ce00870f
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Funding
- National Natural Science Foundation of China [21975103, 21905108]
- Young and Middle-aged Leading Talents and the Team of Science and Technology Innovation of Jilin Provincial Science and Technology Department [20200301039RQ]
- Research on Science and Technology from the Education Department of Jilin Province [JJKH20200412KJ, JJKH20200414KJ]
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The tetraphenylethylene-based covalent organic framework (TTPE-COF) with a rhomboid-shaped framework shows promising performance in gas storage and volatile organic compound capture, as well as good selectivity and detection capability for Fe3+. It has potential applications in adsorbents and fluorescent sensors.
A tetraphenylethylene-based covalent organic framework (TTPE-COF) with a rhomboid-shaped framework is constructed by a Schiff base reaction. Due to its porous structure and high surface area (681.27 m(2) g(-1)), the TTPE-COF will be a meritorious adsorbent for gas storage (CO2 of 485.89 mg g(-1) at 45 bar/318 K) and volatile organic compound (VOC) capture (benzene of 5.80 mmol g(-1) and toluene of 5.20 mmol g(-1) at 293 K). Furthermore, the TTPE-COF has good selectivity and detection effect for Fe3+, and the detection limit (LOD) of Fe3+ is 3.07 mu M. The TTPE-COF has potential applications in adsorbents and fluorescent sensors.
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