Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 19, Issue 33, Pages 7172-7175Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ob00940k
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Funding
- Deutsche Forschungsgemeinschaft (DFG) [182849149 - SFB 953, AM407]
- Government of the Russian Federation [02.A03.21.0011]
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A facile synthesis of N-arylated carbazoles via ladderization of fluorinated oligophenylenes is described, involving two subsequent nucleophilic substitutions triggered by an electronic transfer from dimsyl anions. The reaction allows effective one-pot formation of at least six C-N bonds with pronounced selectivity to the C-F bond placement.
Herein, we describe a facile synthesis of N-arylated carbazoles via ladderization of fluorinated oligophenylenes. The reaction consists of two subsequent nucleophilic substitutions triggered by an electronic transfer from dimsyl anions. The reaction allows the effective one-pot formation of at least six C-N bonds with pronounced selectivity to the C-F bond placement.
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