Journal
CHEMICAL SOCIETY REVIEWS
Volume 50, Issue 18, Pages 10594-10673Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cs01354d
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- Nanyang Technological University (NTU)
- Singapore Ministry of Education [MOE2018-T2-2-048(S)]
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This review presents the recent developments of [4n+2]-electron systems of heavier heterocycles involving group 13-15 elements, including synthesis, spectroscopic data, structural parameters, computational data, and reactivity.
While the implication of the aromaticity concept has been dramatically expanded to date since its emergence in 1865, the classical [4n+2]/4n-electron counting protocol still plays an essential role in evaluating the aromatic nature of compounds. Over the last few decades, a variety of heavier heterocycles featuring the formal [4n+2] pi-electron arrangements have been developed, which allows for assessing their aromatic nature. In this review, we present recent developments of the [4n+2]-electron systems of heavier heterocycles involving group 13-15 elements. The synthesis, spectroscopic data, structural parameters, computational data, and reactivity are introduced.
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