4.7 Article

An air-tolerant polymer gel-immobilized iridium photocatalyst with pumping recyclability properties

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 63, Pages 7762-7765

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03020e

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A novel methacrylate-based cross-linked polymer gel containing an iridium photocatalyst exhibited air tolerance and recyclability due to its tunable swelling and deswelling ability. Photocatalytic activity of the polymer gel was demonstrated in E-to-Z isomerisation and azide-alkene [2+3] cycloaddition reactions.
A novel methacrylate-based cross-linked polymer gel bearing an iridium photocatalyst showed air tolerance and pumping recyclability features through its tunable swelling and deswelling ability. The photocatalytic activity of the polymer gel was demonstrated through an E-to-Z isomerisation reaction and in an azide-alkene [2+3] cycloaddition.

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