Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 70, Pages 8770-8773Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03015a
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The gold(i)-catalysed tandem transmetallation reaction allows for the synthesis of a variety of novel arsinocarbyne complexes, including heterocyclic phenarsazininyl and arsolyl examples.
Gold(i)-catalysed tandem transmetallation (Sn -> Au -> As) of the stannylcarbyne [W(equivalent to(CSnBu3)-Bu-n)(CO)(2)(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM equivalent to CAsR2, including unusual heterocyclic phenarsazininyl and arsolyl examples.
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