4.6 Article

Ruthenium-catalysed oxidative coupling of vinyl derivatives and application in tandem hydrogenation

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 11, Issue 17, Pages 5772-5776

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cy01282g

Keywords

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Funding

  1. CNRS
  2. Universite de Rennes 1
  3. ANR-JCJC [ANR-19-CE07-0039]
  4. Fondation Rennes 1
  5. Region Bretagne [1715]
  6. Agence Nationale de la Recherche (ANR) [ANR-19-CE07-0039] Funding Source: Agence Nationale de la Recherche (ANR)

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A new method for the synthesis of 1,3-diene building blocks using ruthenium-catalyzed oxidative homo- and cross-coupling is reported, which mainly produces the E,E isomer. This methodology also allows for the synthesis of adipic acid ester derivatives in a one-pot fashion after in situ ruthenium-catalyzed hydrogenation.
The first ruthenium-catalyzed oxidative homo- and cross-coupling of exclusive vinyl derivatives giving highly valued 1,3-diene building blocks is reported. The catalytic system is based on readily available reagents and it mainly delivers the E,E isomer. This methodology also enables the synthesis of adipic acid ester derivatives in a one-pot fashion after in situ ruthenium-catalyzed hydrogenation.

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