4.8 Review

Emerging beyond-graphene elemental 2D materials for energy and catalysis applications

Journal

CHEMICAL SOCIETY REVIEWS
Volume 50, Issue 19, Pages 10983-11031

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cs00821g

Keywords

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Funding

  1. ITC via the Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM)
  2. City University of Hong Kong [9610478, 1886921, 9380100]
  3. Science Technology and Innovation Committee of Shenzhen Municipality [JCYJ20200109143412311]

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This review highlights the recent advances in energy and catalysis applications of elemental 2D materials beyond graphene, discussing their advantages, structure, properties, material preparation, and various applications in energy harvesting, storage, and catalysis. The challenges and future perspectives for the development of elemental 2D materials in energy and catalysis are also addressed.
Elemental two-dimensional (2D) materials have emerged as promising candidates for energy and catalysis applications due to their unique physical, chemical, and electronic properties. These materials are advantageous in offering massive surface-to-volume ratios, favorable transport properties, intriguing physicochemical properties, and confinement effects resulting from the 2D ultrathin structure. In this review, we focus on the recent advances in emerging energy and catalysis applications based on beyond-graphene elemental 2D materials. First, we briefly introduce the general classification, structure, and properties of elemental 2D materials and the new advances in material preparation. We then discuss various applications in energy harvesting and storage, including solar cells, piezoelectric and triboelectric nanogenerators, thermoelectric devices, batteries, and supercapacitors. We further discuss the explorations of beyond-graphene elemental 2D materials for electrocatalysis, photocatalysis, and heterogeneous catalysis. Finally, the challenges and perspectives for the future development of elemental 2D materials in energy and catalysis are discussed.

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