Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 72, Pages 9120-9123Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03719f
Keywords
-
Categories
Funding
- JST-CREST [JPMJCR20B6]
- JSPS [JP18H01993, JP20H04805, JP20K21205, JP19H04565]
- Mitsubishi Foundation
Ask authors/readers for more resources
Certain metal sandwich complexes undergo dimerization through metal-metal bond formation, with a unique axially chiral structure derived from a heterometal arrangement in a mixed-metal cluster observed in the case of a reductive dimerization of mixed-metal Pd2Pt or PdPt2 sandwich complexes.
Certain metal sandwich complexes undergo dimerization through metal-metal bond formation. Here, we found that a reductive dimerization of mixed-metal Pd2Pt or PdPt2 sandwich complexes proceeds through selective Pt-Pt bond formation. A restricted rotation at the Pt-Pt bond of the PdPt2 dimer gave a unique axially chiral structure derived from a heterometal arrangement in a mixed-metal cluster.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available