Journal
REACTION CHEMISTRY & ENGINEERING
Volume 6, Issue 11, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1re00304f
Keywords
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Funding
- Japan Society for the Promotion of Science (KAKENHI) [19K15613]
- AIST research fellowship, Exploratory Research
- Grants-in-Aid for Scientific Research [19K15613] Funding Source: KAKEN
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A tri-n-octyl(sulfobutyl)phosphonium-based ionic liquid catalyst forms a triphasic system with glycerol and oleic acid, effectively catalyzing their condensation reaction. Additionally, a monomer structurally analogous to the catalyst is co-polymerized with divinylbenzene to create a cross-linked polyelectrolyte that promotes the same reaction.
A tri-n-octyl(sulfobutyl)phosphonium-based ionic liquid catalyst (ILC1) formed a triphasic system with glycerol and oleic acid, dissolving both reactants and effectively catalysing their condensation to produce glyceryl oleate. An ILC monomer structurally analogous to ILC1 was co-polymerised with divinylbenzene to afford a cross-linked polyelectrolyte promoting the above reaction at <100 degrees C.
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