4.6 Review

Architecture engineering of carbonaceous anodes for high-rate potassium-ion batteries

Journal

CARBON ENERGY
Volume 3, Issue 4, Pages 554-581

Publisher

WILEY
DOI: 10.1002/cey2.99

Keywords

carbonaceous anodes; electronic conductivity; high-rate performance; ion diffusivity; potassium-ion batteries

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This review discusses how advanced carbonaceous anode materials, developed through architectural engineering, can improve the high-rate performance of KIBs. It also highlights the beneficial concepts extracted from recent progress, as well as focusing on recent engineering strategies, structural innovations, and related advances in carbonaceous anodes for high-rate KIBs.
The limited lithium resource in earth's crust has stimulated the pursuit of alternative energy storage technologies to lithium-ion battery. Potassium-ion batteries (KIBs) are regarded as a kind of promising candidate for large-scale energy storage owing to the high abundance and low cost of potassium resources. Nevertheless, further development and wide application of KIBs are still challenged by several obstacles, one of which is their fast capacity deterioration at high rates. A considerable amount of effort has recently been devoted to address this problem by developing advanced carbonaceous anode materials with diverse structures and morphologies. This review presents and highlights how the architecture engineering of carbonaceous anode materials gives rise to high-rate performances for KIBs, and also the beneficial conceptions are consciously extracted from the recent progress. Particularly, basic insights into the recent engineering strategies, structural innovation, and the related advances of carbonaceous anodes for high-rate KIBs are under specific concerns. Based on the achievements attained so far, a perspective on the foregoing, and proposed possible directions, and avenues for designing high-rate anodes, are presented finally.

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