Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 7, Pages 874-878Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201701325
Keywords
Catenanes; Templated synthesis; Synthetic methods; Spiro compounds
Categories
Funding
- Netherlands Research Council (NWO) (ECHO) [711.012.009]
Ask authors/readers for more resources
A templated backfolding concept to construct a [2]catenane was attempted via a quasi[1]catenane showing an inverted spiro geometry. The template is covalently connected to the ketal-connected semi-perpendicular-arranged linear precursors and spatially directs the sterically congested backfolding macrocyclizations that are required to give a quasi[1]catenane. So far, we are unable to hydrolyze the cyclic ketal to liberate the [2]catenane.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available