Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2017, Issue 15, Pages 2108-2111Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201601607
Keywords
Radicals; Single-electron transfer; Radical reactions; 5-exo-dig; Cyclization
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Funding
- European Union for a Career Integration Grant [PCIG13-GA-2013-631556]
- Leverhulme Trust [4500284613]
- AstraZeneca
- School of Chemistry at the University of Manchester
- Department of Chemistry, King Faisal University
- Engineering and Physical Sciences Research Council [1781625] Funding Source: researchfish
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A visible-light-mediated synthesis of 5-methylene-pyrrolidinones is reported. This constitutes to the first reported example of a 5-exo-dig hydroamination reaction involving a nitrogen-centered radical.
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