Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2017, Issue 15, Pages 2122-2125Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201601604
Keywords
Photocatalysis; Carbenoids; Cyclization; Radicals; Cyclopropane
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Funding
- ICIQ Foundation
- CERCA Programme (Generalitat de Catalunya)
- MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-0319]
- CELLEX Foundation through the CELLEX-ICIQ high-throughput experimentation platform
- ICIQ
- CELLEX Foundation
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A new protocol for the catalytic cyclopropanation of alpha,beta-unsaturated carbonyl compounds with diiodomethane by means of photoredox catalysis has been successfully developed. The transformation is characterized by its mild conditions, functional-group compatibility, and excellent selectivity profile.
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