Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2017, Issue 25, Pages 3549-3564Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700285
Keywords
Annulation; Transition-metal catalysis; Rhenium; C-H activation; C-C activation
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Funding
- National Natural Science Foundation of China [U1362110, 51534004, 21322203, 21272238, 21521002]
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Transition-metal-catalyzed intra- and intermolecular annulation reactions have been widely investigated, owing to their important applications in the synthesis of natural products, pharmaceuticals, and functional materials. Rhenium lies at the interface of early and late transition metals in the Periodic Table, with its unique properties, such as low electronegativity and ability to activate C-H and C-C bonds, enabling a series of atom- and step-economical annulation reactions from simple substrates. This Microreview aims to summarize the impressive progress in rhenium-catalyzed annulation reactions in recent years from our own viewpoints and perspectives.
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