4.5 Review

Online Monitoring of Polymerizations: Current Status

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2017, Issue 44, Pages 6474-6482

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700851

Keywords

Continuous flow; Polymerization; Copolymerization; Flow reactors; Automation

Funding

  1. Fonds Wetenschappelijk Onderzoek (FWO)
  2. BOF funds of Hasselt University

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Polymerizations are challenging to monitor online. Next to spectrometric information, which indicates the composition, progress, and identity of polymers, other characterization methods also need to be employed for paramount monitoring. Information on molecular weight distributions and end group patterns are often indispensable for accurate process (and product) control. An overview of existing characterization methods, which can be used for online monitoring, and eventually for automating, multistep polymerizations, is given.

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