Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2017, Issue 22, Pages 3197-3210Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700300
Keywords
Synthetic methods; Photochemistry; Nitrogen heterocycles; Indoles; Carbazoles; Clausenawalline D
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Funding
- Swiss National Science Foundation [200020-1129617]
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The photolysis of N-aryltriazoles and N-arylbenzotriazoles leads to indoles and carbazoles, respectively. Because libraries of triazoles can be accessed rapidly, for example by the copper-catalyzed [3+2] cycloaddition reaction between alkynes and azides, this reaction allows the preparation of indoles in a single operation, by the simultaneous photolysis of the precursor library. As an example of such a synthesis of carbazoles, we prepared for the first time clausenawalline D, an antimalarial alkaloid that was recently isolated.
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