Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2017, Issue 43, Pages 6375-6381Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700990
Keywords
Alkaline earth metals; Imidazole; Heterogeneous catalysis; Quinoline; Metal-organic frameworks
Categories
Funding
- Ministerio de Economia y Competitividad [CTQ2015-66624-P]
- University of Alicante [VIGROB-285]
- Ministerio de Educacion, Cultura y Deporte [FPU15/06040]
Ask authors/readers for more resources
This article details the development of heterogeneous catalysts based on calcium and barium in combination with the organic linker 1,3-bis(carboxymethyl)imidazolium (bcmim). The linker and the materials from alkaline earth metals are easily prepared under very smooth conditions. The use of linkers with different counterions (Cl or Br) provided different materials. Calcium- and barium-based catalysts were successfully employed in the preparation of quinoline derivatives from ketones and 2-aminoarylaldehydes or 2-aminoarylketones. In general, barium-based catalysts provided better results than calcium, although the latter are an excellent complement for certain substrates. Thus, a notable feature of such catalysts is the possibility of accessing a variety of complementary heterogeneous catalytic systems, rendering the catalysis adaptive to the reactant.||||||
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available