4.6 Article

The carbon-carbon triple bond as a tool to design organic semiconductors for photovoltaic applications: an assessment of prospects and challenges

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 9, Issue 45, Pages 16164-16186

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1tc02958d

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Funding

  1. Fondo Ricerca di Base [2019]

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Research interest in alkyne-containing organic semiconductors has resurged, with significant advancements in their optoelectronic performance. Emphasis has been placed on studying the impact of substituting C-C bonds with alkyne linkages on photovoltaic properties, while also discussing the challenges and opportunities in developing pi-conjugated alkynes.
Alkyne-containing organic semiconductors are once again becoming the subject of intense research focus, and recent advances have significantly enhanced their performance in optoelectronics. This Perspective focuses on the results achieved in organic solar cells and offers a critical insight into the architecture-properties-device response of these materials; emphasis is also given to studies investigating the effect of substituting single and/or olefinic C-C bonds for alkyne linkages on photovoltaic properties. In addition, this Perspective discusses the challenges and opportunities in advancing the synthetic strategies to develop pi-conjugated alkynes.

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