Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2017, Issue 36, Pages 5357-5369Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700878
Keywords
Glycosylation; Carbohydrates; Disaccharides; Glycomimetics; Phosphorus; Glycosides
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Funding
- Averroes-ERASMUS MUNDUS program
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The synthesis of pseudodisaccharides based on an oxaphosphinane heterocycle is described. Disaccharide mimetics 5 and 6 were readily obtained through glycosylation of a hydroxy group with appropriately protected furanosyl or pyranosyl carbohydrates using a trichloroacetamidate coupling strategy. Selective or complete deprotection then produced the chiral pseudodisaccharides in good yields.
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