Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 84, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03451k
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Funding
- Spanish Ministry of Science, Innovation and Universities (MCIU) (MCIU/AEI/FEDER, UE) [PGC2018-096880-A-I00, PGC2018-099470-B-I00]
- Spanish MINECO/AEI
- European Union (ESF) for a Ramon y Cajal contract [RYC-2015-19035]
- Alfonso Martin Escudero Foundation
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In this study, molecular tweezers for fullerene recognition were developed based on 2,2 '-bipyridine-bearing corannulene motifs, allowing for selective syn or anti confirmation through Cu(i) coordination/decoordination. This control mechanism enables effective metal-triggered ON/OFF molecular tweezers for fullerene recognition.
Herein, we report molecular tweezers for fullerene recognition based on 2,2 '-bipyridine-bearing corannulene motifs. The syn or anti confirmation can be selected simply by Cu(i) coordination/decoordination, thus controlling the fullerene recognition capability of the system on demand and leading to the formation of effective metal-triggered ON/OFF molecular tweezers.
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