Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 79, Pages 10202-10205Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04011a
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Funding
- National Natural Science Foundation of China [21573126, 21903048, 22002069]
- Natural Science Foundation of Shandong Province, China [ZR2020QB062]
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A novel supramolecular chiral hydrogel with enhanced emission was successfully obtained through the co-assembly of achiral thiobarbituric acid-modified gold nanoclusters with chiral histidine molecules. Chirality transfer in the supramolecular hydrogels was achieved through pi-pi stacking and intermolecular H-bonding based on molecular recognition, providing a creative strategy for building chiral nanocluster-based materials.
A novel supramolecular chiral hydrogel with enhanced emission was obtained by the co-assembly of achiral thiobarbituric acid-modified gold nanoclusters (TBA-AuNCs) with chiral histidine molecules. Chirality transfer from histidine to the supramolecular hydrogels was achieved through the pi-pi stacking and intermolecular H-bonding based on molecular recognition. This work gives a creative strategy for the building of chiral nanocluster-based materials.
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