Journal
NANOSCALE
Volume 13, Issue 37, Pages 15770-15780Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nr04602k
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Funding
- Singapore Ministry of Education [MOE2019-T2-2-032]
- Singapore National Research Foundation [NRF-CRP14-2014-03]
- Faculty of Engineering and Physical Sciences at the University of Southampton
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This study characterized the structure and surface chemistry of CsPbBr3 nanocrystals with controlled diameters, demonstrating Cs-133 NMR as a highly sensitive probe of nanocrystal size. A combined multinuclear solid state NMR and XPS approach was used to study the nanocrystal surface and ligands, revealing Cs-Br rich surface with vacancies passivated by DDAB ligands. The CsPbBr3 NCs were shown to be structurally stable under ambient conditions for up to 6 months, despite some particle agglomeration.
This investigation has characterised the structure and surface chemistry of CsPbBr3 nanocrystals with controlled diameters between 6.4 to 12.8 nm. The nanocrystals were investigated via a thorough Cs-133 solid state NMR and nuclear relaxation study, identifying and mapping radially-increasing nanoscale disorder. This work has formalised Cs-133 NMR as a highly sensitive probe of nanocrystal size, which can conveniently analyse nanocrystals in solid forms, as they would be utilised in optoelectronic devices. A combined multinuclear solid state NMR and XPS approach, including Cs-133-H-1 heteronuclear correlation 2D (HETCOR) NMR, was utilised to study the nanocrystal surface and ligands, demonstrating that the surface is Cs-Br rich with vacancies passivated by didodecyldimethylammonium bromide (DDAB) ligands. Furthermore, it is shown that a negligible amount of phosphonate ligands remain on the powder nanocrystal surface, despite the key role of octylphosphonic acid (OPA) in controlling the colloidal nanocrystal growth. The CsPbBr3 NCs were shown to be structurally stable under ambient conditions for up to 6 months, albeit with some particle agglomeration.
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