Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 11, Pages 1504-1509Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201700064
Keywords
Iron; Reduction; Hydrogen; Photocatalysis; Photosensitizers
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Funding
- German ministry Bundesministerium fur Bildung und Forschung (BMBF)
- German-Swedish project SusChEmX [05K14PP1]
- cooperative research project 3MET/TRR88 [C2]
- Deutsche Forschungsgemeinschaft (DFG) research unit FOR1405 [TP5]
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For the first time, the potential of noble-metal-free iron-based photosensitizers for photocatalytic water reduction by using homo- and heteroleptic carbene complexes was proven. The development of a facile synthesis route for such carbene complexes was delineated. The complexes were investigated by UV/Vis and fluorescence spectroscopy, DFT calculations, cyclic voltammetry, and X-ray absorption spectroscopy. Their catalytic performance was compared to that of established noble-metal-containing photosensitizers such as [Ir(ppy)(2)(bpy)][PF6] (Hppy = 2-phenylpyridine, bpy = 2,2'-bipyridine).
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