Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 3-4, Pages 248-258Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201701194
Keywords
Electron transfer; Molecular magnetism; Photomagnetism; Cyano-metallates; Spin crossover
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Funding
- University of Bordeaux
- Centre National de la Recherche Scientifique (CNRS)
- Region Aquitaine
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Since the report of photomagnetic effects in Prussian blue Fe/Co networks 20 years ago by the Japanese group of Hashimoto, a substantial family of molecular analogs have been obtained and characterized. These compounds offer a unique opportunity to follow metal-to-metal electron transfer by investigating their structural, spectroscopic, electrochemical and magnetic properties. We propose an overview of recent results in order to highlight the common features of these coordination compounds, as well as the differences, with the well-known class of photomagnetic coordination compounds based on spin-crossover.
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