4.5 Article

Comparative Study of Equivalent Circuit Models Performance in Four Common Lithium-Ion Batteries: LFP, NMC, LMO, NCA

Journal

BATTERIES-BASEL
Volume 7, Issue 3, Pages -

Publisher

MDPI
DOI: 10.3390/batteries7030051

Keywords

lithium-ion battery; battery modeling; equivalent circuit model; hysteresis effect; cell chemistry; LFP; NMC; LMO; NCA

Funding

  1. Department of Chemical Engineering at the University of Waterloo
  2. Canada Research Chair Tier I-Zero-Emission Vehicles and Hydrogen Energy System [950-232215]
  3. Natural Sciences and Engineering Research Council of Canada (NSERC) [RGPIN-2020-04149]

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The study conducted experiments to investigate the performance of different ECMs on four types of Li-ion battery chemistries. The results showed that all three models had low errors for all chemistries, with better performance in dynamic current profiles. The 1RC with hysteresis ECM performed best for LFP and NCA, while the 1RC ECM was most suited for NMC and LMO.
Lithium-ion (Li-ion) batteries are an important component of energy storage systems used in various applications such as electric vehicles and portable electronics. There are many chemistries of Li-ion battery, but LFP, NMC, LMO, and NCA are four commonly used types. In order for the battery applications to operate safely and effectively, battery modeling is very important. The equivalent circuit model (ECM) is a battery model often used in the battery management system (BMS) to monitor and control Li-ion batteries. In this study, experiments were performed to investigate the performance of three different ECMs (1RC, 2RC, and 1RC with hysteresis) on four Li-ion battery chemistries (LFP, NMC, LMO, and NCA). The results indicated that all three models are usable for the four types of Li-ion chemistries, with low errors. It was also found that the ECMs tend to perform better in dynamic current profiles compared to non-dynamic ones. Overall, the best-performed model for LFP and NCA was the 1RC with hysteresis ECM, while the most suited model for NMC and LMO was the 1RC ECM. The results from this study showed that different ECMs would be suited for different Li-ion battery chemistries, which should be an important factor to be considered in real-world battery and BMS applications.

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