Journal
NEW JOURNAL OF CHEMISTRY
Volume 45, Issue 39, Pages 18491-18496Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj03341g
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Funding
- Russian Foundation for Basic Research [19-33-90171, CCU.21.0017 (075-15-2021-670)]
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This study reveals that the interaction of 1,4-dichloro-3a,6a-diaza-1,4-diphosphapentalenes with metallic Na or Li or the naphthalene-Na anion-radical salt in THF proceeds through several successive stages, ultimately resulting in a stable aromatic 1,2,3-azadiphospholide ion.
The interaction of 1,4-dichloro-3a,6a-diaza-1,4-diphosphapentalenes with metallic Na or Li or the naphthalene-Na anion-radical salt in THF proceeds through several successive stages: dehalogenation, two types of rearrangement of the heteropentalene fragment to form 1,6-diaza-3a,6a-diphosphapentalene- and 1,4-diaza-3a,6a-diphosphapentalene derivatives, and subsequent cleavage of the heteropentalene framework to give a stable aromatic 1,2,3-azadiphospholide ion.
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