Enhanced visible light photocatalytic water-splitting activity over LaVO4/g-C3N4 with oxygen defects

A heterojunction structure LaVO4/g-C3N4 composite with oxygen defects was successfully prepared. The characterization results show that the recombination of electron-hole pairs could be inhibited by the heterojunction structure. The LaVO4/g-C3N4 composite shows superior photocatalytic water splitting performance for the generation of hydrogen and oxygen under visible light irradiation. Experimental data show that under visible light irradiation, the hydrogen and oxygen evolution rates of the LVOCN1 composite are much higher than those of fresh carbon nitride. Moreover, the photocatalytic activity of LaVO4/g-C3N4 composites could be significantly enhanced by O defects. Mechanism studies display that the possible mechanism of the photocatalytic water splitting reaction is the Z scheme mechanism.

Automated summary

The LaVO4/g-C3N4 composite with heterojunction structure and oxygen defects inhibits the recombination of electron-hole pairs, showing superior photocatalytic water splitting performance under visible light irradiation. The photocatalytic activity of the composite is significantly enhanced by oxygen defects, and the Z scheme mechanism is proposed for the photocatalytic water splitting reaction.