4.8 Article

Limonene dioxide as a building block for 100% bio-based thermosets

Journal

GREEN CHEMISTRY
Volume 23, Issue 24, Pages -

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc02732h

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Funding

  1. Ministere de l'Education et de la Recherche
  2. Centre National de la Recherche Scientifique (CNRS)
  3. University Cote d'Azur
  4. French Government, through the UCAJEDI Investments in the Future project [ANR-15IDEX-01]
  5. UCA JEDI IDEX

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This study valorizes the benign epoxidation of (R)-(+)-limonene to generate novel bio-resourced limonene dioxide monomers. The racemic limonene dioxide was cured with glutaric and dimethylglutaric anhydrides leading to thermosets with a high T-g and good mechanical properties.
This study valorises the benign epoxidation of (R)-(+)-limonene to generate novel bio-resourced limonene dioxide monomers. Without additional steps of separation or functionalization, the racemic limonene dioxide was cured with glutaric and dimethylglutaric anhydrides leading to thermosets with a high T-g (similar to 98 degrees C) and good mechanical properties (sigma = 27 MPa; epsilon = 3.5%; E = 1150 MPa; E ' = 1650 MPa, Shore D = 78).

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