4.7 Article

Stable Zr-UiO-67 constructed through polymeric network assisted post-synthetic modification and its wettability modulation

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 84, Pages 11021-11024

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04063d

Keywords

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Funding

  1. Natural Science Foundation Project of Chongqing [cstc2019jcyj-msxmX0309]
  2. Fundamental Research Funds for the Central Universities [2020CDJQY-A033]

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The stable Zr-UiO-67 is prepared by introducing a fluorine-containing layer on its surface through a polymeric network assisted post-synthetic modification (PSM) strategy. The MOFs exhibit superlyophobic behavior towards liquids with a surface tension threshold of over 48 mN m(-1), making them a potential choice for separating various liquid-liquid mixtures and emulsions due to the protective layer improving their stability in acidic, alkaline, and saline environments.
Stable Zr-UiO-67 is prepared by introducing a fluorine-containing layer on its surface through a polymeric network assisted post-synthetic modification (PSM) strategy. The stability of the MOFs in acidic, alkaline and saline environments is improved because of the existence of a protective layer. The MOFs are superlyophobic towards liquids with a surface tension threshold of over 48 mN m(-1), making them a potential choice for separating various liquid-liquid mixtures and emulsions.

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