Journal
POLYMER CHEMISTRY
Volume 12, Issue 40, Pages 5747-5751Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1py00928a
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Funding
- University of Pavia
- INSTM (Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali)-Regione Lombardia
- MIUR
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In this study, the polymerization of electron-poor olefins was successfully achieved under free-radical conditions using arylazo sulfones as visible light photoinitiators. The process proceeded smoothly at room temperature without the need for any co-initiators or additives, resulting in high molecular weight polymers obtained in excellent yields.
The polymerization of a broad range of electron-poor olefins has been achieved under free-radical conditions by using arylazo sulfones as visible light photoinitiators. The process proceeds smoothly at room temperature both in bulk and in the presence of solvents upon irradiation with a 40 W Kessil lamp (456 nm, blue light) in the absence of any co-initiators or additives. High molecular weight polymers are obtained in excellent yields.
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