Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 85, Pages 11173-11176Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04886d
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Funding
- Arnold and Mabel Beckman Foundation through a Beckman Young Investigator Award
- American Chemical Society Petroleum Research Fund [61638-DNI7]
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In this study, a new mechanophore platform based on a masked 2-furylcarbinol derivative was reported, which efficiently releases phenol and arylamine payloads following mechanical activation. This platform incorporates a 5-aryloxy group as an electron-rich substituent to accelerate molecular release.
Polymers that release small molecules in response to mechanical force are attractive materials for a wide variety of applications. Here, we report a new mechanophore platform based on a masked 2-furylcarbinol derivative that incorporates a 5-aryloxy group, which serves as both an electron-rich substituent to accelerate molecular release and the position of polymer attachment proximal to the furan-maleimide junction. The mechanophore is readily synthesized and efficiently releases both phenol and arylamine payloads following mechanical activation.
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