Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 90, Pages 11968-11971Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04551b
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- Ministry of Science and Technology of Taiwan [MOST 108-2218-E-110-013-MY3, MOST 110-2636-E-007-020, MOST 110-2622-8-007-015]
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The synthesis of two carbazole-thiophene-based conjugated microporous polymers with varying degrees of planarity affected their porous structure, hydrogen-evolution rate, and photocatalytic stability.
We report the synthesis of two carbazole-thiophene-based conjugated microporous polymers (Cz-3Th and Cz-4Th CMPs) with different degrees of planarity for photocatalytic hydrogen evolution from water. Depending upon the building linker's planarity, we found that the porous structure, hydrogen-evolution rate, and photocatalytic stability of the resultant CMPs varied.
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