4.7 Article

Halogenated sodium/lithium monocarba-closo-decaborates: syntheses, characterization, and solid-state ionic conductivity

Related references

Note: Only part of the references are listed.
Article Materials Science, Multidisciplinary

Modulating composite polymer electrolyte by lithium closo-borohydride achieves highly stable solid-state battery at 25°C

Kepan Bao et al.

Summary: Rational composite design is crucial for developing high-performance composite polymer electrolytes for solid-state lithium metal batteries. The introduction of Li closo-borohydride into the polymer electrolyte has shown to greatly enhance Li+ conduction properties, while density functional theory calculations have revealed the mechanism behind this improvement. In addition, the novel composite polymer electrolyte exhibits excellent electrochemical, thermal, and mechanical stability, making it highly compatible with various electrode materials.

SCIENCE CHINA-MATERIALS (2022)

Article Chemistry, Physical

Intermolecular interaction characteristics of the all-carboatomic ring, cyclo[18]carbon: Focusing on molecular adsorption and stacking

Zeyu Liu et al.

Summary: The research found that cyclo[18]carbon has a strong tendency to adsorb small molecules in its condensed phase, where dispersion attraction plays a leading role in binding interactions and the electrostatic effect also influences the configuration of molecular complexes. Additionally, two cyclo[18]carbon molecules can form a stable dimer through pi-pi stacking effect.

CARBON (2021)

Article Chemistry, Physical

Na+ diffusivity in carbon-substituted nido- and closo-hydroborate salts: Pulsed-field-gradient NMR studies of Na-7-CB10H13 and Na2 (CB9H10)(CB11H12)

A. Skripov et al.

Summary: The research measured the diffusion coefficients of Na+ cations in compounds Na-2(CB9H10)(CB11H12) and Na-7-CB10H13, revealing exceptionally high diffusion rates exceeding 2 x 10(-6) cm(2)/s. Additionally, both compounds exhibited superionic conductivity near the order-disorder phase transition temperature of 320 K. The study also found that the transition from low-T ordered phase to high-T disordered phase was accompanied by a sudden acceleration of jump rates.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Multidisciplinary

Nido-Hydroborate-Based Electrolytes for All-Solid-State Lithium Batteries

Seyed Hosein Payandeh et al.

Summary: This study introduces hydroborate-based solid electrolytes for high voltage all-solid-state sodium batteries and proposes the cost-effective building block LiB11H14 nido-hydroborate for lithium systems with high ionic conductivity. Strategies to improve stability by modifying chemical structure are discussed, and compatibility with metallic anodes is demonstrated through galvanostatic cycling. Additionally, the electrolyte Li-2(B11H14)(CB11H12) shows promising performance in a proof-of-concept half cell with TiS2 cathode.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Nanoscience & Nanotechnology

Iodine-Substituted Lithium/Sodium closo-Decaborates: Syntheses, Characterization, and Solid-State Ionic Conductivity

Shouhu Li et al.

Summary: Solid-state electrolytes based on closo-decaborates are of interest due to their impressive room-temperature ionic conductivity, stability, and flexibility. Iodine substitution in closo-decaborates was found to increase thermal decomposition temperature. Li-2[B10I10] exhibits enhanced ionic conductivity compared to the parent compound, showing potential for high-temperature battery applications.

ACS APPLIED MATERIALS & INTERFACES (2021)

Review Electrochemistry

Electrolyte/Electrode Interfaces in All-Solid-State Lithium Batteries: A Review

Yuepeng Pang et al.

Summary: All-solid-state lithium batteries have great potential for higher energy density and safety, but the poor electrode compatibility of solid electrolytes may cause electrolyte/electrode interface degradation, leading to battery failure. Mechanistic analyses and strategies for enhancing electrolyte/electrode interfaces are crucial for the future development of these batteries.

ELECTROCHEMICAL ENERGY REVIEWS (2021)

Article Chemistry, Multidisciplinary

Closo-Hydroborate Sodium Salts as an Emerging Class of Room-Temperature Solid Electrolytes

Matteo Brighi et al.

CELL REPORTS PHYSICAL SCIENCE (2020)

Article Chemistry, Physical

Theoretical Study of Halogenated B12HnX(12-n)2- (X = F, Cl, Br)

Manish Sharma et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2019)

Article Electrochemistry

Room-temperature-operating Na solid-state battery with complex hydride as electrolyte

Fabrizio Murgia et al.

ELECTROCHEMISTRY COMMUNICATIONS (2019)

Article Nanoscience & Nanotechnology

In Situ Formed Li-B-H Complex with High Li-Ion Conductivity as a Potential Solid Electrolyte for Li Batteries

Mengfei Zhu et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Chemistry, Multidisciplinary

A High-Performance Li-B-H Electrolyte for All-Solid-State Li Batteries

Fuqiang Lu et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Review Chemistry, Multidisciplinary

Controlled functionalization of o-carborane via transition metal catalyzed B-H activation

Yangjian Quan et al.

CHEMICAL SOCIETY REVIEWS (2019)

Article Chemistry, Physical

A mixed anion hydroborate/carba-hydroborate as a room temperature Na-ion solid electrolyte

Matteo Brighi et al.

JOURNAL OF POWER SOURCES (2018)

Article Chemistry, Inorganic & Nuclear

Modified Anion Packing of Na2B12H12 in Close to Room Temperature Superionic Conductors

Yolanda Sadikin et al.

INORGANIC CHEMISTRY (2017)

Article Multidisciplinary Sciences

Multifunctionality of silver closo-boranes

Mark Paskevicius et al.

NATURE COMMUNICATIONS (2017)

Article Chemistry, Physical

Halogenated Sodium-closo-Dodecaboranes as Solid-State Ion Conductors

Bjarne R. S. Hansen et al.

CHEMISTRY OF MATERIALS (2017)

Article Chemistry, Inorganic & Nuclear

Microwave-Assisted Iodination: Synthesis of Heavily Iodinated 10-Vertex and 12-Vertex Boron Clusters

Marcus A. Juhasz et al.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY (2016)

Review Chemistry, Inorganic & Nuclear

Metal boranes: Progress and applications

Bjarne R. S. Hansen et al.

COORDINATION CHEMISTRY REVIEWS (2016)

Article Chemistry, Multidisciplinary

Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions

Wan Si Tang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2015)

Article Chemistry, Physical

Altering the structural properties of A2B12H12 compounds via cation and anion modifications

Wan Si Tang et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2015)

Article Chemistry, Multidisciplinary

Exceptional Superionic Conductivity in Disordered Sodium Decahydro-closo-decaborate

Terrence J. Udovic et al.

ADVANCED MATERIALS (2014)

Article Chemistry, Multidisciplinary

Update 1 of: Chemistry of the Carba-closo-dodecaborate(-) Anion, CB11H12-

Christos Douvris et al.

CHEMICAL REVIEWS (2013)

Article Chemistry, Multidisciplinary

Thermal Stability of Li2B12H12 and its Role in the Decomposition of LiBH4

Mark P. Pitt et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Multiwfn: A multifunctional wavefunction analyzer

Tian Lu et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2012)

Review Chemistry, Multidisciplinary

Carbaboranes as Pharmacophores: Properties, Synthesis, and Application Strategies

Matthias Scholz et al.

CHEMICAL REVIEWS (2011)

Review Chemistry, Multidisciplinary

Boron in Drug Discovery: Carboranes as Unique Pharmacophores in Biologically Active Compounds

Fatiah Issa et al.

CHEMICAL REVIEWS (2011)

Article Chemistry, Multidisciplinary

IMPROVED SYNTHESIS OF [closo-1-CB9H10](-) ANION AND NEW C-SUBSTITUTED DERIVATIVES

Bryan Ringstrand et al.

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS (2009)

Review Chemistry, Multidisciplinary

Density functionals with broad applicability in chemistry

Yan Zhao et al.

ACCOUNTS OF CHEMICAL RESEARCH (2008)