Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 88, Pages 11613-11616Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04541e
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Funding
- CSIR, Delhi [MLP-0203]
- DST-INSPIRE
- UGC
- IIT Roorkee [FIG-100810]
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A regioselective C8 linear olefination of isoquinoline-1H-2-one with terminal (aromatic and aliphatic) alkynes is reported under Co(iii) catalysis. This study is the first to demonstrate the C8 functionalization of isoquinolone using non-noble transition metal complexes. Experimental and computational mechanistic studies have been conducted to elucidate the reaction pathway.
A regioselective C8 linear olefination of isoquinoline-1H-2-one with terminal (aromatic and aliphatic) alkynes is reported under Co(iii) catalysis. This is an exclusive report on the C8 functionalization of isoquinolone using non-noble transition metal complexes. Experimental and computational mechanistic studies have also been performed to depict the reaction pathway.
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