Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 9, Issue 41, Pages 14885-14896Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1tc03337a
Keywords
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Funding
- National Natural Science Foundation of China [21965015, 21764007, 21662018]
- Project of the Education Department of Jilin Province, China [JJKH20180777KJ]
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The research shows that M(HH)(3)M compounds induced by external electric field are potential nonlinear optical materials. These compounds exhibit different characteristics in off and on forms, resulting in significant improvements in static first hyperpolarizabilities.
Exploration of novel molecular switches is an ongoing hot issue in molecular electronics. Alkalides and electrides are two typical representatives of excess electron compounds. It was found that M(HF)(3)M (M = Li or Na) induced by an oriented external electric field are good candidates for inorganic multi-response nonlinear optical (NLO) molecular switches. Their off forms (C-3h) exhibit electride-like super alkali earth atom characteristics, while their on forms (C-3v) exhibit charming superalkalide (M = Na or Li) or superalkali electride characteristics (M = Li). The increases of the static first hyperpolarizabilities (beta e0) from off to on forms constitute a 2-3 orders of magnitude improvement for both M = Li and Na. These extremely large differences in beta e0 reinforce the potential of M(HF)(3)M for applications in excellent multi-response nonlinear optical materials.
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