4.7 Article

Light-controlled interconversion between a [c2]daisy chain and a lasso-type pseudo[1]rotaxane

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 92, Pages 12317-12320

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04419b

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Funding

  1. Deutsche Forschungsgemeinschaft [434455294]
  2. European Union through the NOAH project (H2020-MSCA-ITN) [765297]

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This study presents a light-responsive molecular structure that can be switched between two different conformations under light, showing potential for various applications.
A light-responsive self-complementary crown ether/ammonium conjugate bearing an arylazopyrazole photoswitch as a spacer can be switched between a [c2]daisy chain (E-isomer) and a lasso-type pseudo[1]rotaxane (Z-isomer) by light.

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