Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 93, Pages 12532-12535Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc05557g
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Funding
- Fonds der Chemischen Industrie
- German Research Foundation (DFG) through the Emmy Noether Programme [HI 2063/1-1]
- Karlsruhe Nano Micro Facility (KNMF), a Helmholtz Research Infrastructure at Karlsruhe Institute of Technology (KIT)
- state of Baden-Wurttemberg through bwHPC
- DFG [INST 40/467-1 FUGG]
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The paper discusses several attempts to reduce bulky carbazolyl diiodoalane, revealing the effects of different reducing agents and observing various reaction outcomes.
We report details of our attempts to reduce the bulky carbazolyl diiodoalane [R-AlI2]. The reducing agents employed include KC8, Cp*Co-2 and the Mg(i) compound [((BDI)-B-Mes)Mg](2). The use of KC8 allowed the spectroscopic observation of the alanediyl [R-Al]. With Cp*Co-2 as the reducing agent, the alanediyl [R-Al] was obtained as a crystalline material in low yield, but paramagnetic impurities remained. When diiodoalane [R-AlI2] was treated with [((BDI)-B-Mes)Mg](2), no reduction but a 2 : 1 addition was observed.
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