Journal
POLYMER CHEMISTRY
Volume 12, Issue 42, Pages 6050-6070Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1py00834j
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Funding
- National Natural Science Foundation of China [21675091, 21874078, 22074072]
- Taishan Young Scholar Program of Shandong Province [tsqn20161027]
- Key Research and Development Project of Shandong Province [2016GGX102028, 2016GGX102039, 2017GGX20111]
- Major Science and Technology Innovation Project of Shandong Province [2018CXGC1407]
- First Class Discipline Project of Shandong Province
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Micron-sized porous polymer microspheres, such as PGMA microspheres, are a hot research topic in the field of polymer materials due to their wide range of applications. By introducing different functional groups, the properties of microspheres can be improved, expanding their applications in various fields. Poly(GMA-co-EGDMA) composite microspheres show promising application prospects in the future.
As a new kind of functional material, micron-sized porous polymer microspheres are a hot research topic in the field of polymer materials. Poly(glycidyl methacrylate)microspheres have been widely used in many fields, such as immobilization of bioactive substances (enzymes, cells, proteins, antibodies, etc.). There are three main preparation methods of PGMA microspheres: suspension polymerization, the seed expansion method, and precipitation polymerization. By introducing different functional groups into microspheres, the hydrophobicity, solubility and biocompatibility of the microspheres were improved, and the microspheres with different characteristics could be applied as high performance chromatographic fillers and catalyst carriers and in biomedical and adsorbent fields. In this paper, the development history, preparation methods, functionalization and application of poly(GMA-co-EGDMA) composite microspheres are reviewed systematically and comprehensively. Finally, the existing application materials based on PGMA microspheres are summarized and analyzed, and the application prospect of poly(GMA-co-EGDMA) composite microspheres in the future is analyzed.
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