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Application of Covalent Organic Framework Materials as Heterogeneous Ligands in Organic Synthesis

Journal

CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 41, Issue 10, Pages 3826-3843

Publisher

SCIENCE PRESS
DOI: 10.6023/cjoc202107030

Keywords

covalent organic framework materials; heterogeneous catalysis; organic synthesis; heterogeneous ligands

Funding

  1. National Natural Science Foundation of China [21272053]
  2. Natural Science Foundation of Hebei Province [B2020205026]

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COFs, as a new type of crystalline porous material composed of light elements through covalent bonds, play an important role in catalytic reactions, with advantages such as high specific surface area, high porosity, and high crystallinity. Recent research has focused on using COFs as heterogeneous ligands to support different metal ions for catalyzing various organic reactions.
Covalent organic frameworks (COFs) are a new type of crystalline porous material composed of light elements (C, O, N, B, etc.) through covalent bonds. Because of its high specific surface area, high porosity, and high crystallinity, COFs have advantages that other traditional materials can not match. By using COFs as heterogeneous ligands to support metal ions, different types of catalytic reactions can be realized, and the catalyst can be reused. The latest research progress of COFs as heterogeneous ligands supporting different metal ions to catalyze various organic reactions is summarized.

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