4.4 Review

Recent advances in compatibility and toughness of poly(lactic acid)/poly(butylene succinate) blends

Journal

E-POLYMERS
Volume 21, Issue 1, Pages 793-810

Publisher

WALTER DE GRUYTER GMBH
DOI: 10.1515/epoly-2021-0072

Keywords

PLA; PBS; physical blending; chemical modification; compatibilization

Funding

  1. National Natural Science Foundation of China [51273060]
  2. Key Project of Science and Technology Research Plan of Hubei Provincial Education Department, the Open Fund of Hubei Provincial Key Laboratory of Green Materials for Light Industry.

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This article presents physical and chemical modification methods to improve the performance of PLA/PBS blends, including the effects of fillers, compatibilizing agents, and the formation of cross-linked/branched structures. Effective strategies are provided to enhance the compatibility between PLA and PBS components and improve overall properties, with high research and application prospects.
Poly(butylene succinate) (PBS) has good impact strength and high elongation at break. It is used to toughen biodegradable poly(lactic acid) (PLA) materials because it can considerably improve the toughness of PLA without changing the biodegradability of the materials. Therefore, this approach has become a hotspot in the field of biodegradable materials. A review of the physical and chemical modification methods that are applied to improve the performance of PLA/PBS blends based on recent studies is presented in this article. The improvement effect of PLA/PBS blends and the addition of some common fillers on the physical properties and crystallization properties of blends in the physical modification method are summarized briefly. The compatibilizing effects of nanofillers and compatibilizing agents necessary to improve the compatibility and toughness of PLA/PBS blends are described in detail. The chemical modification method involving the addition of reactive polymers and low-molecular-weight compounds to form cross-linked/branched structures at the phase interface during in situ reactions was introduced clearly. The addition of reactive compatibilizing components is an effective strategy to improve the compatibility between PLA and PBS components and further improve the mechanical properties and processing properties of the materials. It has high research value and wide application prospects in the modification of PLA. In addition, the degradation performance of PLA/PBS blends and the methods to improve the degradation performance were briefly summarized, and the development direction of PLA/PBS blends biodegradation performance research was prospected.

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