4.8 Article

When SF5 outplays CF3: effects of pentafluorosulfanyl decorated scorpionates on copper

Related references

Note: Only part of the references are listed.
Review Chemistry, Multidisciplinary

Fluorinated Pyrazoles: From Synthesis to Applications

Pavel K. Mykhailiuk

Summary: Fluorinated pyrazoles are increasingly important in various fields, with a focus on novel synthetic approaches, reaction mechanisms, and unexplored classes of these compounds.

CHEMICAL REVIEWS (2021)

Article Chemistry, Multidisciplinary

The Supramolecular Structural Chemistry of Pentafluorosulfanyl and Tetrafluorosulfanylene Compounds

Phil Liebing et al.

Summary: The analysis of crystal structures of SF5- or SF4-containing molecules showed that these groups are often surrounded by hydrogen or other fluorine atoms, and F...F contacts are important in many compounds. Additionally, repeating structural motifs formed by contacts between SF5 groups were identified, including different supramolecular dimers and infinite chains.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Multidisciplinary

Chemoselective Hydro(Chloro)pentafluorosulfanylation of Diazo Compounds with Pentafluorosulfanyl Chloride

Jia-Yi Shou et al.

Summary: Pentafluorosulfanyl chloride (SF5Cl) is commonly used in organic synthesis, but its preparation often involves hazardous reagents and specialized equipment. Researchers have developed a safe and practical method to prepare a stable and easy-to-handle solution of SF5Cl without the need for gas-phase reagents, demonstrating its potential through synthetic applications.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Inorganic & Nuclear

Single-Crystal-to-Single-Crystal Transformations of Metal-Organic-Framework-Supported, Site-Isolated Trigonal-Planar Cu(I) Complexes with Labile Ligands

Ricardo A. Peralta et al.

Summary: MOFs offer a unique matrix for isolating and stabilizing specific transition-metal complexes, and an in situ anion metathesis strategy facilitates the post-synthetic modification of Cu(I) complexes appended to MOFs. By exchanging coordinated chloride for weakly coordinating anions in the presence of CO or ethylene, labile MOF-appended Cu(I) complexes featuring CO or ethylene ligands are prepared and structurally characterized. This allows small and moderately sized molecules to access the isolated Cu(I) sites, displacing the place-holder CO ligand, mimicking ligand-exchange processes in Cu-centered catalysis.

INORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Overcoming Fundamental Limitations in Adsorbent Design: Alkene Adsorption by Non‐porous Copper(I) Complexes

Devaborniny Parasar et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

2,2,2-Trifluorodiazoethane (CF3CHN2): A Long Journey since 1943

Pavel K. Mykhailiuk

CHEMICAL REVIEWS (2020)

Article Biochemistry & Molecular Biology

A SF5Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes

Maria Talavera et al.

MOLECULES (2020)

Article Chemistry, Inorganic & Nuclear

Isolable Copper(I) η2-Cyclopropene Complexes

Anurag Noonikara-Poyil et al.

INORGANIC CHEMISTRY (2020)

Article Chemistry, Organic

Regioselective Gold-Catalyzed Hydration of CF3- and SF5-alkynes

Melissa Cloutier et al.

ORGANIC LETTERS (2019)

Article Chemistry, Multidisciplinary

Towards the online computer-aided design of catalytic pockets

Laura Falivene et al.

NATURE CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Making the SF5 Group More Accessible: A Gas-Reagent-Free Approach to Aryl Tetrafluoro-λ6-sulfanyl Chlorides

Cody Ross Pitts et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Review Materials Science, Multidisciplinary

Pentafluorosulfanyl group: an emerging tool in optoelectronic materials

Julian M. W. Chan

JOURNAL OF MATERIALS CHEMISTRY C (2019)

Article Chemistry, Inorganic & Nuclear

Carbonyl complexes of copper(I) stabilized by bridging fluorinated pyrazolates and halide ions

Devaborniny Parasar et al.

DALTON TRANSACTIONS (2019)

Article Chemistry, Inorganic & Nuclear

Luminescent Charge-Neutral Copper(I) Phenanthroline Complexes with Isocyanoborate Ligand

Kin-Cheung Chan et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Low Heat of Adsorption of Ethylene Achieved by Major Solid-State Structural Rearrangement of a Discrete Copper(I) Complex

Naleen B. Jayaratna et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Organic

Silver-Promoted Synthesis of 5-[(Pentafluorosulfanyl)methyl]-2-oxazolines

Audrey Gilbert et al.

ORGANIC LETTERS (2018)

Article Chemistry, Multidisciplinary

Pentafluorosulfanyl Substituents in Polymerization Catalysis

Philip Kenyon et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Review Chemistry, Medicinal

Application of the Pentafluorosulfanyl Group as a Bioisosteric Replacement

Munia F. Sowaileh et al.

CHEMMEDCHEM (2017)

Review Chemistry, Multidisciplinary

Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes

Concepcion Alonso et al.

CHEMICAL REVIEWS (2015)

Article Chemistry, Inorganic & Nuclear

Green Phosphorescence and Electroluminescence of Sulfur Pentafluoride-Functionalized Cationic Iridium(III) Complexes

Nail M. Shavaleev et al.

INORGANIC CHEMISTRY (2015)

Article Chemistry, Organic

Synthesis of SF5-Substituted Tetrapyrroles, Metalloporphyrins, BODIPYs, and Their Dipyrrane Precursors

Hartwig R. A. Golf et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

Article Chemistry, Multidisciplinary

Improving the Fatigue Resistance of Diarylethene Switches

Martin Herder et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

Synthesis and Characterization of 2-Pyridylsulfur Pentafluorides

Oleksandr S. Kanishchev et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Review Chemistry, Multidisciplinary

Preparation and Utility of Organic Pentafluorosulfanyl-Containing Compounds

Paul R. Savoie et al.

CHEMICAL REVIEWS (2015)

Review Chemistry, Multidisciplinary

Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond

Xiao Liu et al.

CHEMICAL REVIEWS (2015)

Article Chemistry, Organic

Diastereoselectivity in the Staudinger reaction of pentafluorosulfanylaldimines and ketimines

Alexander Penger et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

Selective Detection of Ethylene Gas Using Carbon Nanotube-based Devices: Utility in Determination of Fruit Ripeness

Birgit Esser et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Review Chemistry, Inorganic & Nuclear

Synthetic chemistry and biological activity of pentafluorosulphanyl (SF5) organic molecules

Stefano Altomonte et al.

JOURNAL OF FLUORINE CHEMISTRY (2012)

Review Chemistry, Multidisciplinary

Aromatic Trifluoromethylation with Metal Complexes

Olesya A. Tomashenko et al.

CHEMICAL REVIEWS (2011)

Review Multidisciplinary Sciences

Catalysis for fluorination and trifluoromethylation

Takeru Furuya et al.

NATURE (2011)

Review Chemistry, Physical

A Combined Charge and Energy Decomposition Scheme for Bond Analysis

Mariusz P. Mitoraj et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2009)

Review Chemistry, Inorganic & Nuclear

π Back-Bonding in Dibenzyl-β-diketiminato Copper Olefin Complexes

Paul O. Oguadinma et al.

ORGANOMETALLICS (2009)

Review Chemistry, Inorganic & Nuclear

Structurally characterized coinage-metal-ethylene complexes

H. V. Rasika Dias et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2008)

Article Chemistry, Organic

Convenient route to trifluoromethyl-substituted cyclopropane derivatives

Pavel K. Mykhailiuk et al.

SYNTHESIS-STUTTGART (2008)

Article Chemistry, Inorganic & Nuclear

A convenient and efficient method for incorporation of pentafluorosulfanyl (SF5) substituents into aliphatic compounds

William R. Dolbier et al.

JOURNAL OF FLUORINE CHEMISTRY (2006)

Review Chemistry, Multidisciplinary

Stereoselective cyclopropanation reactions

H Lebel et al.

CHEMICAL REVIEWS (2003)

Article Chemistry, Multidisciplinary

Copper(I)-homoscorpionate catalysts for the preferential, kinetically controlled cis cyclopropanation of α-olefins with ethyl diazoacetate

MM Díaz-Requejo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)