4.7 Article

Visualisation of helical structures of poly(diphenylacetylene)s bearing chiral amide pendants by atomic force microscopy

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 92, Pages 12266-12269

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc05341h

Keywords

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Funding

  1. JSPS KAKENHI [21K14671, 21K04685, 21H04691, 20H00345, 20K05321, 20H05212, 20K15172, 18K19422, 17H05058, 18H05209]
  2. Sumitomo Foundation [190382, 181041]
  3. Grants-in-Aid for Scientific Research [21K04685, 21K14671, 21H04691, 20H00345, 17H05058, 18K19422, 20K15172, 20K05321, 20H05212] Funding Source: KAKEN

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The study visualized the helical structures of poly(diphenylacetylene)s bearing optically active substituents linked through amide bonds and with a helicity memory using atomic force microscopy. The polymers self-assembled into an ordered 2D monolayer on highly oriented pyrolytic graphite upon exposure to solvent vapor, with the helical pitch and handedness (right- and left-handed) directly revealed at molecular resolution for the first time.
The helical structures of poly(diphenylacetylene)s bearing optically active substituents linked through amide bonds and with a helicity memory have been visualised using atomic force microscopy. The polymers self-assembled into an ordered 2D monolayer on highly oriented pyrolytic graphite upon exposure to solvent vapour, whose helical pitch and handedness (right- and left-handed) were for the first time directly revealed at molecular resolution.

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