Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 90, Pages 11988-11991Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc05221g
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Funding
- National Natural Science Foundation of China [21772186]
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The synthesis of 1,4-enynes via nickel-catalyzed cross-coupling of allylic alcohols with alkynylzinc reagents exhibits high regio- and E/Z-selectivity, especially when aryl-substituted allylic alcohols are employed. The method also shows a wide scope of substrates and good compatibility of functional groups.
Synthesis of 1,4-enynes was performed via nickel-catalyzed cross-coupling of allylic alcohols with alkynylzinc reagents. The reaction features high regio- and E/Z-selectivity when aryl-substituted allylic alcohols were employed. The method also exhibits a wide scope of substrates and good compatibility of functional groups.
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