Journal
DALTON TRANSACTIONS
Volume 50, Issue 45, Pages 16499-16503Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt03357c
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Funding
- Science Challenge Project [TZ2018004]
- National Natural Science Foundation of China [21875110, 22075143]
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Novel potynitro azoxypyrazole-based energetic compounds 1,2-bis (4-nitro-1H-pyrazol-5-yl) diazene 1-oxide and 1,2-bis (1,4-dinitro-1H-pyrazol-3-yl) diazene 1-oxide were synthesized from 5-amino-pyrazole-4-carbonitrile by optimized reactions, showing high thermal stability and detonation performance, enriching the content of energetic materials.
Novel potynitro azoxypyrazole -based energetic compounds 1,2-bis (4-nitro-1H-pyrazol-5-yl) diazene 1-oxide (3) and 1,2-bis (1,4-dinitro-1H-pyrazol-3-yl) diazene 1-oxide (4) were synthesized from 5-amino-pyrazole-4-carbonitrile by optimized reactions. Their structures were characterized by elemental analysis and single-crystal X-ray diffraction techniques. Compound 3 exhibits high thermal stability (239 degrees C), low mechanical sensitivity (IS = 22 J, FS = 240 N) and moderate detonation performance (D-v = 8272 m s(-1), P = 28.1 GPa). Compound 4 shows moderate thermal stability (161 degrees C), decent mechanical sensitivity and higher detonation performance (D-v = 9228 m s(-1) , P = 38.7 GPa) compared to that of RDX. These newly developed strategies for constructing novel energetic compounds enrich the content of the ever-expanding energetic materials.
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