Journal
SOFT MATTER
Volume 17, Issue 45, Pages 10322-10333Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1sm00719j
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Funding
- German Research Foundation (DFG) [MC 9/22-1]
- MIUR (Italian Ministry of Education, University and Research) project PRIN [2017KL4EF3]
- GNFM of Italian INdAM
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In this study, a parallel is drawn between ferromagnetic materials and nematic liquid crystals confined on curved surfaces within the framework of continuum theory. It is shown that the combination of extrinsic curvature of the shell and the out-of-plane component of the director field leads to chirality effects. Furthermore, the different nature of the order parameter results in different textures on surfaces with the same topology.
Within the framework of continuum theory, we draw a parallel between ferromagnetic materials and nematic liquid crystals confined on curved surfaces, which are both characterized by local interaction and anchoring potentials. We show that the extrinsic curvature of the shell combined with the out-of-plane component of the director field gives rise to chirality effects. This interplay produces an effective energy term reminiscent of the chiral term in cholesteric liquid crystals, with the curvature tensor acting as a sort of anisotropic helicity. We discuss also how the different nature of the order parameter, a vector in ferromagnets and a tensor in nematics, yields different textures on surfaces with the same topology as the sphere. In particular, we show that the extrinsic curvature governs the ground state configuration on a nematic spherical shell, favouring two antipodal disclinations of charge +1 on small particles and four +1/2 disclinations of charge located at the vertices of a square inscribed in a great circle on larger particles.
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