Benefit of ion imprinting technique in solid-phase extraction of heavy metals, special focus on the last decade

Because of its many advantages, solid phase extraction (SPE) is considered to be the best process for removing heavy metals from water. Ion-imprinted polymers (IIPs) have been broadly used in the last decade as SPE adsorbents for the retention of metals ions from aqueous solutions. This itemized review list thorough literature over the last decade from 2010 until present and highlights the main results related to adsorption studies where IIPs are used as SPE adsorbents for the selective separation of heavy metals. In the first part of this review elaboration methods, components, and major polymerization techniques to produce IIPs have been described. In the second part, synthesis parameters, adsorption performance and a descriptive analysis of SPE of heavy metals by IIPs have been provided. In this review it is underlined that there are many parameters to optimize in order to obtain the required performance of the IIPs. These parameters are mainly linked to synthesis process and one of the most important is the synthesis of new ligands to improve the selectivity with respect to the target ion.

Automated summary

Solid phase extraction (SPE) is considered the best process for removing heavy metals from water, with Ion-imprinted polymers (IIPs) being widely used as SPE adsorbents for this purpose. This review focuses on literature from the past decade, emphasizing the importance of optimizing synthesis parameters and the synthesis of new ligands for improved selectivity in heavy metal separation using IIPs.