Conformational-change-induced selectivity enhancement of CAU-10-PDC membrane for H2/CH4 and CO2/CH4 separation

The separation of H 2 /CH4 or CO2/CH4 is critical to the purification of natural gas. Herein, we report on novel membranes with a metal-organic framework of CAU-10-PDC for the separation of these two mixtures. The dense CAU-10-PDC membranes are fabricated on a porous alumina support using the seeded growth method. An unex-pected increase in selectivity was observed while testing mixed gas permeation with either H 2 /CH4 or CO2/CH4 at a molar ratio of 50:50. Steady-state selectivity reached 101 for H 2 /CH4 and 62 for CO2 /CH4. Ideal selectiv-ity measured from single gas permeation reached 475 for H 2 /CH4 and 288 for CO2/CH4. Molecular dynamics simulations and time-resolved X-ray diffraction with a synchrotron radiation source were used to probe confor-mational changes in CAU-10-PDC induced by exposure to CH4. When exposed to an atmosphere containing CH4, CAU-10-PDC presented a change in the space group (from I 4 1 / amd to I 4 1 ), which drastically reduced the pore limiting diameter from 4.15 to 2.95 & ANGS;, rendering the channel nearly impermeable to CH4.

Automated summary

This study presents novel CAU-10-PDC membranes for efficient separation of H2 / CH4 and CO2 / CH4 mixtures with significantly improved selectivity. Experimental and simulation methods were used to investigate the conformational changes of CAU-10-PDC induced by exposure to CH4, revealing insights into the membrane's permeability performance.