Journal
RSC ADVANCES
Volume 11, Issue 61, Pages 38667-38673Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ra07014b
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Funding
- National Natural Science Foundation of China [21462002]
- Jiangxi Province Office of Education Support Program [GJJ190757, GJJ190788]
- Graduate Innovation Project of Gannan Medical University [YC2021-X014]
- Practice and Innovation Training Program for College Students in Jiangxi Province [201910413013]
- Scientific Research Project of Gannan Medical University [ZD201819]
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The direct C-H trifluoromethylation of alkynes and quinoxalinones has been achieved using a graphene oxide/Langlois' reagent system, resulting in the formation of olefinic C-CF3 to access a series of 3-trifluoroalkylated quinoxalin-2(1H)-ones.
The direct C-H trifluoromethylation of alkynes and quinoxalinones has been achieved using a graphene oxide/Langlois' reagent system. This multi-component tandem reaction using graphene oxide as the catalyst and Langlois' reagent as the robust CF3 radical source results in the formation of olefinic C-CF3 to access a series of 3-trifluoroalkylated quinoxalin-2(1H)-ones.
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