Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 99, Pages 13594-13597Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06307c
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Funding
- JST PRESTO [JPMJPR18TB, JPMJPR18T5]
- JSPS KAKENHI [18K19071]
- Kanazawa University SAKIGAKE Project 2020
- Grants-in-Aid for Scientific Research [18K19071] Funding Source: KAKEN
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Phthalocyanine ruthenium complexes have been identified as red-light activatable catalysts for trifluoromethylation reactions, enabling the chlorotrifluoromethylation of alkenes without sacrificial reducing reagents. This reaction shows good compatibility with a blue-light-absorbing substrate, unlike traditional photoreaction conditions where the substrate decomposes completely under blue light irradiation.
Phthalocyanine ruthenium complexes were identified as red-light activatable catalysts for trifluoromethylation reactions. The red-light mediated chlorotrifluoromethylation of alkenes could proceed without any sacrificial reducing reagents. This reaction exhibited good compatibility with a blue-light-absorbing substrate, while under irradiation with blue light, i.e., under traditional photoreaction conditions, this substrate decomposed completely.
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